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Z.-S. Wu, W. Ren*, L. Gao, J. Zhao, Z. Chen, B. Liu, D. Tang, B. Yu, C. Jiang, H.-M. Cheng*, 
Acs Nano 2009, 3 (2): 411-417.  
DOI:10.1021/nn900020u  [PDF]

发布时间:2016-03-18    栏目名称:2009

Z.-S. Wu, W. Ren*, L. Gao, J. Zhao, Z. Chen, B. Liu, D. Tang, B. Yu, C. Jiang, H.-M. Cheng*, 
Acs Nano 2009, 3 (2): 411-417.  
DOI:10.1021/nn900020u  [PDF] 

   
                 
   
 
Abstract: 
We developed a hydrogen arc discharge exfoliation method for the synthesis of graphene sheets (GSs) with excellent electrical conductivity and good thermal stability from graphite oxide (GO), in combination with solution-phase dispersion and centrifugation techniques. It was found that efficient exfoliation and considerable deoxygenation of GO, and defect elimination and healing of exfoliated graphite can be simultaneously achieved during the hydrogen arc discharge exfoliation process. The GSs obtained by hydrogen arc discharge exfoliation exhibit a high electrical conductivity of~2×103 S/cm and high thermal stability with oxidization resistance temperature of 601 °C, which are much better than those prepared by argon arc discharge exfoliation (~2×102 S/cm, 525 °C) and by conventional thermal exfoliation (~80 S/cm, 507 °C) with the same starting GO. These results demonstrate that this hydrogen arc discharge exfoliation method is a good approach for the preparation of GSs with a good quality.

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