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H.-W. Liang, W. Wei, Z.-S. Wu, X. Feng*, K. Müllen*, 
Journal of the American Chemical Society 2013, 135 (43): 16002-16005. 
DOI: 10.1021/ja407552k  [PDF]

发布时间:2016-03-18    栏目名称:2013

H.-W. Liang, W. Wei, Z.-S. Wu, X. Feng*, K. Müllen*,
Journal of the American Chemical Society 2013, 135 (43): 16002-16005.
DOI: 10.1021/ja407552k  [PDF]

Abstract
A family of mesoporous nonprecious metal (NPM) catalysts for oxygen reduction reaction (ORR) in acidic media, including cobalt–nitrogen-doped carbon (C–N–Co) and iron–nitrogen-doped carbon (C–N–Fe), was prepared from vitamin B12 (VB12) and the polyaniline-Fe (PANI-Fe) complex, respectively. Silica nanoparticles, ordered mesoporous silica SBA-15, and montmorillonite were used as templates for achieving mesoporous structures. The most active mesoporous catalyst was fabricated from VB12 and silica nanoparticles and exhibited a remarkable ORR activity in acidic medium (half-wave potential of 0.79 V, only ∼58 mV deviation from Pt/C), high selectivity (electron-transfer number >3.95), and excellent electrochemical stability (only 9 mV negative shift of half-wave potential after 10 000 potential cycles). The unprecedented performance of these NPM catalysts in ORR was attributed to their well-defined porous structures with a narrow mesopore size distribution, high Brunauer–Emmett–Teller surface area (up to 572 m2/g), and homogeneous distribution of abundant metal–Nx active sites

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