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All-Solid-State Flexible Planar Lithium Ion Micro-Capacitors
Posted:2018-05-31 20:30    Column:2018

S.H. Zheng, J.M. Ma, Z.-S. Wu*, F. Zhou, Y. B. He*, F. Y. Kang, H.-M. Cheng, X. H. Bao
Energy & Environmental Science, 2018, 11, 2001-2009.
DOI:10.1039/C8EE00855H [PDF]


The ever-increasing boom in smart yet miniaturized electronics urgently requires on-chip energy storage systems with high performance, safety, flexibility, and robust integration, but tremendous challenges exist. Here we demonstrate the first prototype of all-solid-state planar lithium ion micro-capacitors (LIMCs) based on interdigital patterns of lithium titanate nanospheres as anode and activated graphene as cathode. The interdigital LIMCs were fabricated via layer-by-layer mask-assisted deposition of graphene and electrode materials, without metal current collector, additive and polymer binder. The as-assembled LIMCs delivered the record volumetric energy density of 53.5 mWh cm-3. Furthermore, they exhibited outstanding mechanical flexibility without performance degradation under repeated bending, superior electrochemical metrics and safety at high temperature of 80 oC due to high-stable ionogel electrolyte and free of separator, and remarkably modular integration of constructing bipolar cells for boosting high voltage, thereby holding great potential for future flexible and wearable electronics.

Dalian Institute of Chemical Physics, CAS
457 Zhongshan Road Dalian, China 116023
E-mail: wuzs@dicp.ac.cn

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